177.  Fe(III)-catalyzed bicyclization of yne-allenones with indoles for the atom-economic synthesis of 3-indolyl

         cyclobutarenes

         Heng Li, Wen-Juan Hao, Guigen Li,* Shu-Jiang Tu, Bo Jiang*

        Front. Chem. 20186, 599 (Research TopicGreen Synthesis of Heterocycles, Invited)          [Link]

         

176.  A new dehydrogenative [4+1] annulation between para-quinone methides (p-QMs) and iodonium ylides for the

         synthesis of  2,3-dihydrobenzofurans

         Yan-Jie Xiong, Shao-Qing Shi, Wen-Juan Hao,* Shu-Jiang Tu,* Bo Jiang*

          Org. Chem. Front. 20185, 3483-3487          [Link]

         

175.  I2-Mediated Iodobenzannulation of Yne-Allenones toward 1-Naphthols and Their Synthetic Application

          Heng Li, Peng Zhou, Feng Xie, Jian-Qiang Hu, Shi-Zhao Yang, You-Jian Wang,* Wen-Juan Hao,

          Shu-Jiang Tu,* Bo Jiang*

          J. Org. Chem. 201883, 13335-13343          [Link]

         

174.  Atom-economic synthesis of cyclobuta[a]naphthalen-4-ols via base-promoted [2 + 2] cycloaddition/

         1,6-nucleophilic addition cascades

           Jia-Yin Wang, Feng-Lie Xie, Jian-Qiang Hu, Shi-Zhao Yang, You-Jian Wang,* Wen-Juan Hao,

         Shu-Jiang Tu,* Bo Jiang*

         Org. Biomol. Chem. 201816, 7104-7108         [Link]

         

173.  NSulfonyl bisimidazoline ligands and their applications in Pd(II)-catalyzed asymmetric addition toward

         αtertiary amines

        Jia-Yin Wang, Meng-Wei Li, Meng-Fan Li, Wen-Juan Hao, Guigen Li,* Shu-Jiang Tu,* Bo Jiang*

        Org. Lett. 201820, 6616-6621          [Link]

         

                 Highlighted by Synfacts (201814(12), 1279, DOI: 10.1055/s-0037-1611321)    [Link]

172.  Visible-light photocatalytic bicyclization of β-alkynyl propenones for accessing diastereoenriched

          syn-fluoren-9-ones

          Zheng-Jia Shen, Hao-Nan Shi, Wen-Juan Hao,* Shu-Jiang Tu,* Bo Jiang*

           Chem. Commun. 201854, 11542-11545          [Link]

         

171.  Recent advances in radical transformations of internal alkynes

          Min-Hua Huang, Wen-Juan Hao, Guigen Li,* Shu-Jiang Tu,* Bo Jiang,*

            Chem. Commun. 201854, 10791-10811 (Invited Review)        [Link]

         

170.   Recent Advances in Radical Enabled Bicyclization and Annulation /1,n-Bifunctionalization Reactions

          Min-Hua Huang, Wen-Juan Hao,* Bo Jiang*

          Chem. Asian J. 201813, 2958- 2977 (Invited Review)          [Link]

                     

169.  Substrate-controlled generation of 3-sulfonylated 1-indenones and 3-arylated (Z)-indenes via Cu-catalyzed

         radical cyclization cascades of o-alkynylbenzonitriles

         Xiao-Tong Zhu,* Qiu-Li Lu, Xiang Wang, Tian-Shu Zhang, Wen-Juan Hao, Shu-Jiang Tu,* Bo Jiang*

        J. Org. Chem. 201883,  9890-9901          [Link]

         

168.  Pd(II)-Catalyzed Carbonyl-Directing Activation of Alkenes: Selective Fluorosulfonylation and 

          Aminosulfonylationof 1,7-Enynes

          Yi-Long Zhu, Chi-Fan Zhu, Peng Zhou, Wen-Juan Hao,* De-Cai Wang, Shu-Jiang Tu,* Bo Jiang*

          J. Org. Chem. 201883, 9641-9653          [Link]

         

167.  Metal-free naphthannulation reactions of yne-allenone esters for accessing polycyclic aromatic hydrocarbons

         Hong-Kai Sha, Ting Xu, Feng Liu, Bu-Zheng Tang, Wen-Juan Hao,* Shu-Jiang Tu,* and Bo Jiang*

          Chem. Commun. 201854, 10415-10418 (Front Cover)      [Link]


        

166.  Catalytic double [2 + 2] cycloaddition relay enabled C-C triple bond cleavage of yne-allenones

         Heng Li, Wen-Juan Hao, Mian Wang, Xue Qin, Shu-Jiang Tu,* Peng Zhou, Guigen Li, Jianyi Wang,* Bo Jiang*

         Org. Lett. 201820, 4362-4366          [Link]

         

165.  Metal-free benzannulation of yne-allenone esters for atom-economic synthesis of functionalized 1-naphthols

  Hong-Kai Sha, Feng Liu, Juan Lu, Zhang-Qin Liu, Wen-Juan Hao,* Jia-Le Tang, Shu-Jiang Tu,* Bo Jiang*

 Green Chem. 201820, 3476-3485 (Front Cover)          [Link]

         

164.  Merging “Anti-Baldwin” 3-exo-dig cyclization with 1,2-alkynyl migration for radical alkylalkynylation of

         unactivated olefins

         Qi Zhao, Xiao-Shuang Ji, Yi-Yun Gao, Wen-Juan Hao,* Ke-Ying Zhang, Shu-Jiang Tu,* Bo Jiang*

         Org. Lett. 201820, 3596-3600          [Link]

         

163.  Visible-light-induced methylsulfonylation/bicyclization of C(sp3)-tethered 1,7-enynes using DMSO/H2O system

         Min-Hua Huang, Chi-Fan Zhu, Chun-Lan He, Yi-Long Zhu*, Wen-Juan Hao, De-Cai Wang*, Shu-Jiang Tu, Bo Jiang*

         Org. Chem. Front. 20185, 1643-1650          [Link]

         

162.  Sulfinate salt-mediated radical relay cyclization of cyclic ethers with 2-alkynylbenzonitriles toward 

         3-alkylated 1-indenones

         Xiao-Tong Zhu, Tian-Shu Zhang, Qi Zhao, Pei-Jun Cai,* Wen-Juan Hao, Shu-Jiang Tu,* Bo Jiang*

          Chem.-Asian J. 201813, 1157-1164          [Link]

         

161.  Double SO2 insertion into 1,7-diynes leading to functionalized naphtho[1,2-c]thiophene 2,2-dioxides

         Ai-Fang Wang, Wen-Juan Hao,* Yi-Long Zhu, Guigen Li, Peng Zhou, Shu-Jiang Tu,* Bo Jiang*

         ACS Omega 20183, 1482-1491           [Link]

              

160.  Oxidative catalytic spiroketalization leading to diastereoselective spiro[benzofuran-2,1'-isochromene]s

         Jiang-Kai Qiu, Wen-Juan Hao, Guigen Li,* Bo Jiang*

         Adv. Synth. Catal. 2018360, 1182-1192        [Link]       

                

159.  Thiazolium salt-catalyzed C−C triple bond cleavage for accessing substituted 1-naphthols via benzannulation

         Peng Zhou, Jia-Yin Wang, Tian-Shu Zhang, Guigen Li,* Wen-Juan Hao, Shu-Jiang Tu,* Bo Jiang*

          Chem. Commun. 2018, 54, 164-167          [Link]

               

158.  Stereoselective synthesis of sulfonated 1-indenones via radical-triggered multi-component cyclization of 

         β-alkynyl propenones

         Zheng-Jia Shen, Ya-Nan Wu,Chun-Lan He, Long He, Wen-Juan Hao, Ai-Fang Wang, Shu-Jiang Tu,* Bo Jiang*

          Chem. Commun. 201854, 445-448 (Front Cover)           [Link]

          

157.  Thiazolium salt-catalyzed [3 + 2 + 1] cyclization for the synthesis of trisubstituted 2-pyrones using arylglyoxals

          as a carbonyl source

          Li-Chen Xu, Peng Zhou, Jia-Zhuo Li, Wen-Juan Hao, Shu-Jiang Tu,* Bo Jiang*

          Org. Chem. Front. 20185, 753-759          [Link]

                

                Selected for the themed collection: Organic Chemistry Frontiers HOT articles for 2017

156.   Tunable Cu(I)-catalyzed site-selective dehydrogenative amination of β,γ-unsaturated hydrazones for

           divergent synthesis of pyrazol-4-ones and 1,6-dihydropyradazines

           Dong-Fang Jiang, Jie-Yu Hu, Wen-Juan Hao,* Shu-Liang Wang, Shu-Jiang Tu,* Bo Jiang*

            Org. Chem. Front. 20185, 189-196          [Link]

                   

155.  Synthesis of Functionalized Benzo[g]indoles and 1-Naphthols via Carbon-Carbon Triple Bond

         Breaking/Rearranging

         Jia-Yin Wang, Peng Zhou, Guigen Li,* Wen-Juan Hao, Shu-Jiang Tu,* Bo Jiang*

         Org. Lett. 201719, 6682-6685          [Link]


             

154.  Silver/Scandium cocatalyzed bicyclization of β-alkynyl ketones leading to benzo[c]xanthenes and

         naphtho[1,2-b]benzofurans

         Ke Chen, Shuai Liu, Dan Wang, Wen-Juan Hao,* Peng Zhou, Shu-Jiang Tu,* Bo Jiang*

         J. Org. Chem. 201782, 11524-11530          [Link]

               

153.  Merging [2 + 2] cycloaddition with radical 1,4-addition: Metal-free access to functionalized

         cyclobuta[a]naphthalen-4-ols

         Feng Liu, Jia-Yin Wang, Peng Zhou, Guigen Li,* Wen-Juan Hao, Shu-Jiang Tu,* Bo Jiang*

         Angew. Chem., Int. Ed. 201756, 15570-15574 (VIP, Front Cover)          [Link]

         

152.  Synergistic silver/scandium catalysis for divergent synthesis of skeletally diverse chromene derivatives

         Shuai Liu, Ke Chen, Xin-Chan Lan, Wen-Juan Hao,* Guigen Li, Shu-Jiang Tu,* Bo Jiang*

         Chem. Commun. 201753, 10692-10695          [Link]

         

151.  Synthesis of tribenzo[b,e,g]phosphindole oxides via radical bicyclization cascades of o-arylalkynylanilines

         Jie Li, Wen-Wen Zhang, Xiao-Jing Wei, Wen-Juan Hao,* Guigen Li, Shu-Jiang Tu,* Bo Jiang*

         Org. Lett. 201719, 4512-4515          [Link]

              

150.  Tunable dimerization and trimerization of β-alkynyl ketones via silver catalysis for accessing spiro and dispiro

         compounds containing 1H-isochromene

         Dan Wang, Shuai Liu, Xin-Chan Lan, Armando Paniagua, Wen-Juan Hao,* Guigen Li, Shu-Jiang Tu,* Bo Jiang*

         Adv. Synth. Catal. 2017359, 3186-3193          [Link]

         

149.  Facile synthesis of benzo[b]thiophenes via metal-free radical-triggered intramolecular C-S bond formation

         Wei Fan, Kwong-Yuen Chen, Qi-Peng Chen, Guigen Li,* Bo Jiang*

         Org. Biomol. Chem. 201715, 6493-6499          [Link]

              

148.  Ag/Brønsted acid co-catalyzed spiroketalization of b-alkynyl ketones towards spiro[chromane-2,1'-

         isochromene] derivatives

         Shuai Liu, Xin-Chan Lan, Ke Chen, Wen-Juan Hao,* Guigen Li, Shu-Jiang Tu,* Bo Jiang,*

         Org. Lett. 201719, 3831-3834          [Link]

               

147.  Radical deaminative ipso-cyclization of 4-methoxyanilines with 1,7-enynes for accessing

          spirocyclohexadienone-containing cyclopenta[c]quinolin-4-ones

          Jie Li, Wen-Wen Zhang, Xiao-Jing Wei, Feng Liu, Wen-Juan Hao, Shu-Liang Wang,* Guigen Li,

          Shu-Jiang Tu,* Bo Jiang*

          J. Org. Chem. 201782, 6621-6628          [Link]

         

146.  Silver-mediated radical 5-exo-dig cyclization of 2-alkynylbenzonitriles: Synthesis of phosphinylated

         1-indenones

          Xiao-Tong Zhu, Qi Zhao, Feng Liu, Ai-Fang Wang, Pei-Jun Cai*, Wen-Juan Hao, Shu-Jiang Tu*, Bo Jiang*

          Chem. Commun. 201753, 6828-6831 (Inside Back Cover)          [Link]

              

145.  Ag-catalyzed difluorohydration of b-alkynyl ketones for diastereoselective synthesis of 1,5-diconboyl

         compounds

         Yi-Long Zhu, Ai-Fang Wang, Jian-Yu Du, Bo-Rong Leng, Shu-Jiang Tu*, De-Cai Wang, Ping Wei*,  

         Wen-Juan Hao, Bo Jiang*

         Chem. Commun. 201753, 6397-6400 (Inside Front Cover)          [Link]

                  

144.  Visible-light photocatalytic bicyclization of 1,7-enynes toward functionalized  sulfone-containing

          benzo[a]fluoren-5-ones

         Min-Hua Huang, Yi-Long  Zhu, Wen-Juan Hao, Ai-Fang Wang, De-Cai Wang*, Feng Liu, Ping Wei,

         Shu-Jiang  Tu*, Bo Jiang*

         Adv. Synth. Catal. 2017359, 2229-2234          [Link]

         

143.  Synthesis of diastereoenriched oxazolo[5,4-b]indoles via catalyst-free multicomponent bicyclizations

          Lu Wang, Li-Xia Shi, Lu Liu, Zhuo-Xuan Li, Ting Xu, Wen-Juan Hao*, Guigen Li, Shu-Jiang Tu*, Bo Jiang*

          J. Org. Chem. 201782, 3605-3611          [Link]

              

142.  Asymmetric [3 + 2] cycloaddition of chiral N-phosphonyl imines with methyl isocyanoacetate for accessing

         to 2-imidazolines with switchable stereoselectivity


141.  Regiospecific synthesis of  1,5,6,7-tetrahydro-4H-indol-4-ones via dehydroxylated [3+2] cyclization of  

         beta-hydroxy ketones with cyclic enaminones

         Xin-Chan Lan, Ting-Ting Chen, Yan Zhao, Yu Wu, Jing Wang, Shu-Jiang Tu, Bo Jiang*, Wen-Juan Hao*

         Tetrahedron Lett. 2017, 58, 1519-1522           [Link]

         

140.  Metal-free benzannulation of 1,7-diynes toward unexpected 1-aroyl-2-naphthaldehydes and their application in

         fused aza-heterocyclic synthesis

         Ai-Fang Wang, Peng Zhou, Yi-Long Zhu, Wen-Juan Hao,* Guigen Li, Shu-Jiang Tu,* Bo Jiang*

         Chem. Commun. 2017, 53, 3369-3372          [Link]

         

139.  I2-Catalyzed sulfenylation of indoles and  pyrroles using triethylammonium thiolates as sulfenylating agents  

         Wei Fan, Zhen Yang, Bo Jiang,* Guigen Li*

          Org. Chem. Front. 20174, 1091-1102          [Link]

         

138.  Radical-enabled bicyclization cascades of oxygen-tethered 1,7-enynes leading to skeletally diverse

         polycyclic chromen-2-ones

         Bo Jiang,* Jie Li, Yuan-Yuan Pan, Wen-Juan Hao, Guigen Li, Shu-Jiang Tu*

         Chin. J. Chem. 201735, 323-334 (Invited, Special Issue: Oxidative Radical Reactions)          [Link]

                      

137.  Chiral GAP catalysts of phosphonylated imidazolidinones and their applications in asymmetric

         Diels-Alder and Friedel-Crafts reactions

         Shuo Qiao, Junming Mo, Cody B. Wilcox, Bo Jiang,* Guigen Li*

         Org. Biomol. Chem. 201715, 1718-1724          [Link]

                      

136.  Silver-mediated radical C(sp3)−H biphosphinylation and nitration of β-alkynyl ketones for accessing

         functional isochromenes

         Jun Sun, Jiang-Kai Qiu, Ya-Nan Wu, Wen-Juan Hao,* Cheng Guo, Guigen Li, Shu-Jiang Tu,* Bo Jiang*

         Org.  Lett. 201719, 754-757          [Link]                          

              

                     X-Mol评述[Link]

135.  Oxidative bicyclization of N-tethered 1,7-enynes toward polycyclic 3,4-dihydroquinolin-2(1H)-ones via 

         site-selective decarboxylative C(sp3)-H functionalization

         Jie Li, Wen-Juan Hao,* Peng Zhou, Yi-Long Zhu, Shu-Liang Wang, Shu-Jiang Tu, Bo Jiang*

         RSC Adv. 201779693-9703          [Link]